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51.
Anmol Shahi Chandresh Dwivedi S.D. Manjare Vaibhav Kulshrestha 《International Journal of Hydrogen Energy》2021,46(13):8852-8863
In overall iodine-sulphur (I-S) cycle (Bunsen reaction), HI decomposition is a serious challenge for improvement in H2 production efficiency. Herein, we are reporting an electrochemical process for HI decomposition and simultaneous H2 and I2 production. Commercial Nafion 117 membrane has been generally utilized as a separator, which also showed huge water transport (electro-osmosis), and deterioration in conductivity due to dehydration. We report sulphonated poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP) (SCP) and sulphonated graphene oxide (SGO) composite stable and efficient polymer electrolyte membrane (PEM) for HI electrolysis and H2 production. Different SCP/SGO composite PEMs were prepared and extensively characterized for water content, ion-exchange capacity (IEC), conductivity, and stabilities (mechanical, chemical, and thermal) in comparison with commercial Nafion117 membrane. Most suitable optimized SCP/SGO-30 composite PEM exhibited 6.78 × 10?2 S cm?1 conductivity in comparison with 9.60 × 10?2 S cm?1 for Nafion® 117. The electro-osmotic flux ofSCP/SGO-30 composite PEM (2.53 × 10?4 cm s?1) was also comparatively lower than Nafion® 117 membrane (2.75 × 10?4 cm s?1). For HI electrolysis experiments, SCP/SGO-30 composite PEM showed good performance such as 93.4% current efficiency (η), and 0.043 kWh/mol-H2 power consumption (Ψ). Further, intelligent architecture of SCP/SGO composite PEM, in which hydrophilic SGO was introduced between fluorinated polymer by strong hydrogen bonding, high efficiency and performance make them suitable candidate for electrochemical HI decomposition, and other diversified electrochemical processes. 相似文献
52.
This paper explores the structural and operational dimensions of the efficiencies of airports. The two-stage procedure is suggested to assess the efficiencies of airports in this study. In the first-stage, Classification and Regression Tree, which is one of the machine-learning approaches used to divide the airports into homogeneous and thus comparable sub-groups. In the second stage, the bootstrap data envelopment analysis approach obtains more precise structural and operational efficiency scores. To illustrate the proposed framework use, we applied it to a real case associated with Turkish airports. The results demonstrate that this framework presents a more comprehensive assessment of airport performance rather than conventional data envelopment analysis models. Moreover, it provides to show the deficiencies of the structural and operational management of airports. The findings can help anywhere airport authorities as well as Turkish airport authorities. 相似文献
53.
The current work introduces an enhancement in the performance of the microbial fuel cell through estimating the optimal set of controlling parameters. The maximization of both power density (PD) and the percentage of chemical oxygen demand (COD) removal were considered as the enhancement in the cell's performance. Three main parameters in terms of performance as well as commercialization are the system's inputs; the Pt which takes the range of 0.1‐0.5 mg/cm2, the degree of sulphonation in sulfonated‐poly‐ether‐ether‐ketone that changes in the range of 20‐80%, and the rate of aeration of cathode which varies between 10 and 150 mL/min. From the experimental dataset, two robust adaptive neuro‐fuzzy inference system models based on the fuzzy logic technique have been constructed. The comparisons between the models' outputs and the experimental data showed well‐fitting in both training and testing datasets. The mean squared errors of the PD model, for testing and whole datasets, were found 2.575 and 0.909 while for the COD model it showed 19.242 and 6.791, respectively. Then, based on the two fuzzy models, a Particle Swarm Optimization algorithm has been used to determine the best parameters that maximize both of the PD and the COD removal of the cell. The optimization process was utilized for single and multi‐object optimization processes. In the single optimization, the resulting maximums of the PD and the COD removal were found 62.844 (mW/m2) and 99.99 (%), respectively. Whereas, in the multi‐object optimization, the values of 61.787 (mW/m2) and 96.21 (%) were reached as the maximums for the PD and COD, respectively. This implies that, in both cases of optimization processes, the adopted methodology can efficiently enhance the microbial fuel cell performances than the previous work. 相似文献
54.
55.
性能效率是APP软件的重要质量属性,但目前缺乏APP软件性能效率的通用模型。分析了APP软件的性能特征,基于ISO/IEC 25010标准提出了APP软件的性能效率模型,定义了APP软件性能效率的子特性和度量指标。基于提出的APP软件性能效率模型,通过实验对APP软件的性能效率进行了度量及相关分析。 相似文献
56.
This study assessed the collection efficiency (CE) of two popularly used sampling devices (BioSampler and Coriolis sampler) for fungal aerosols. Phosphate‐buffered saline (PBS) supplemented with or without surfactant (Tween‐20, Tween‐80, or Triton X‐100) and antifoam agent was prepared and used as collection liquids. The agar impactor (BioStage) was simultaneously operated with liquid‐based samplers to collect fungi from seven sites located at a university building, public library, and animal farming. Fungal concentrations determined by liquid samplers were divided by those by BioStage, and the ratio values represented CE. Results indicate that the CE of BioSampler was superior to that of Coriolis (P = 0.0001) and the PBS containing surfactant collected fungi better than that without surfactant (P < 0.0001), whereas antifoam agent showed no influence (P = 0.8). Moreover, fungal concentrations determined by BioSampler with surfactant‐added PBS were statistically indifferent from those by BioStage (P > 0.05) with a Spearman correlation coefficient of 0.81‐0.83 (P < 0.01). In addition to sampler and collection liquid, sampling location was also identified as a significant CE factor (P = 0.006), implying potential influences by fungal genera in the studied fields. Overall, BioSampler with surfactant‐supplemented PBS (eg, Triton X‐100) is recommended considering the great CE and compatibility with a variety of analytical assays. 相似文献
57.
The aim of this paper is to investigate the long and short-run relationship between spot and futures prices of the energy, precious metals, and base metals markets. We analyze daily data from January 1985 to February 2019. The empirical findings based on the cointegration test, which follows a nonlinear process, suggest that the spot prices of energy and metals assets have long-run relationships with their futures prices. Nonparametric Granger causality test results also indicate bi-directional causality among futures and spot prices. These findings indicate that the energy and metals markets are informationally efficient in the sense of Fama (1970). 相似文献
58.
In this paper, we empirically examine the application of a host of techniques employed to measure price efficiency through long-range dependence using prices of monthly oil contracts. Using a series of methods, we analyse the volatility (daily absolute returns) of WTI and Brent oil prices for nine different contracts with maturity, ranging from 1 to 9 months, during the sample period of 1990-2017. We use bootstrapping to compute the confidence interval of the parameter of long-range dependence. Our results indicate that on an average, there is no long-range dependence in the volatility of oil price contracts at least at the 10-percent level of significance. Moreover, our results of rolling estimates suggest that the normality assumption does not affect the results considerably, and the results are robust to different rolling window sizes. While the results of the efficiency index suggest that the efficiency of oil returns vary with time, the futures contracts for Brent oil are found to be less efficient compared to WTI oil. The long-term futures contracts are more efficient than short-term contracts. 相似文献
59.
通过对往复式活塞压缩机进行改造,在单级活塞压缩系统的基础上搭建了一种中间喷液冷却的准两级压缩系统并在蒸发温度为-20 ℃的工况下进行实验测量,根据实验数据对单级活塞压缩系统和新型中间喷液冷却活塞压缩系统的COP、〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗损失和〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗效率进行计算。结果表明:加入中间喷液冷却系统后,系统的COP由1.27提升至1.36,单位制冷量由155.1 kJ/kg提升至176.7 kJ/kg;单级活塞压缩系统〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗损失较大的部分是压缩机和膨胀阀,分别占压缩机输入〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗的16.2%和14.8%,加入中间喷液冷却系统后压缩机部分的〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗损失明显降低,仅占压缩机输入〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗的3.6%,冷凝器及膨胀阀的〖HT5”,7”〗火〖KG-*3〗用〖HT5”〗损比也有所下降。 相似文献
60.
环境污染治理投资是生态环境保护的资金来源,其投资规模和投资形式对生态效率产生着重大影响。本文构建生态效率测度指标和非期望的超效率SBM模型,测定了长江经济带9省2市的生态效率水平,再利用Tobit模型量化研究环境污染治理投资的总量及各投资形式对生态效率的影响程度,得出长江经济带环境污染治理投资对生态效率具有正向影响但影响程度一般,3种环境污染治理投资类型中的当年完成环保验收项目环保投资对生态效率影响程度最大且显著。 相似文献